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Thursday 27 October 2016

Lesson 5:Periodic Table

Lesson 5: Periodic Table Behavioural objectives: at the end of the lesson, you should be able to 1. Define periodic table 2. State the modern periodic law 3. Discuss the blocks of elements with examples 4. State the group/family of elements on periodic table and name the member of each family. What is periodic table? Periodic table is a chat that shows the arrangement of elements based on their atomic number and chemical properties.
The modern periodic law The modern periodic law states that “chemical properties of elements are a periodic function of their atomic numbers”. The blocks of elements There are four blocks of elements on the periodic table which are: S-block P –block D-block F-block S-block elements: these are elements that their electronic configuration ends on s – orbitals, they can be found on group 1 and 2 of the periodic table. See the image above. They include: hydrogen, lithium, beryllium, sodium, potassium. e.t.c. there electronic configuration looks like this: 1s2,2s2 2p6,3s1 (K) P-block elements: these are elements that their electronic configuration ends on P – orbital. They are located between group 3/13 to 8/18 of the periodic table. That is from aluminium group to the noble gases. D – block elements: these are elements that there electronic configuration ends on d – orbitals, they are also called the transition elements. They are located between group 2 and 3 of the periodic table. Starting from scandium (Sc) to zinc (Zn). See image above. F-block elements: these are the elements that their electronic configuration falls on F orbitals. They are referred to as inner transition elements. They can be found between period 6 and 7 of the periodic table. They are also referred to as lanthanide and actinide series. Isolated to the bottom of the periodic table in the diagram above.

METALS, METALLOIDS AND NON –METALS
Apart from grouping the elements using their blocks, we can also group elements on periodic table into metals, metalloids and non metals.
Metals: these are elements that can give away electrons to become positively charged, they can conduct heat and electricity. They are located between group 1 to 13 of the periodic table. That is from group sodium to aluminium. (see the table above).
Non- metals: these are elements that do accept electron from other elements in order to complete their outermost shell. They do not conduct electricity and heat. They are found between group 14 to 18.ofthe periodic table. That is from carbon to the noble gasses.
Metalloids: these are elements that their characteristics are intermediate between metals and non metals. That is are not completely metals nor complete non-metals in their behaviour. They are found between group 12 to 16 of the periodic table. (see the image above for clarifications).

GROUP AND PERIODS OF ELEMENTS
The most popular and main classification of the periodic table is the group and period. Elements are classified into groups based on the number of electrons they have on their outer most shell while they are also classified into periods based on the number of shells they have.  All elements in a particular group have the same number of electrons in their outer most shell  and all elements in a particular periods have the same number of shell. The group is the vertical column of the periodic table while the horizontal row is the period. There are 8 groups and seven periods on the modern periodic table.

GROUPS AND THEIR PROPERTIES

GROUP ONE ELEMENTS
1.      They include H, Li, Na, K, Rubidium, Caesium and Francium
2.      They are called alkaline metal  
3.      They have 1 electron in their outermost shell
4.      They are all metals which are strongly electropositive except for hydrogen which is a gas but have the atomic number of 1.
5.      They are readily ionized by loss of the single valence electron to become a uni-positive ion.
6.      They are very reactive and form very stable electrovalent compounds
7.      They are good reducing agents

GROUP TWO ELEMENTS
1.      They include Be, Mg, Ca, Sr, Ba and Ra
2.      They are also called alkaline earth metal
3.      They have two valence electrons and ionize by the loss of the two valence electrons to form bivalent ions
4.      They are all metals but less reactive than group one elements. Their  reactivity increases down the group
5.      They are good reducing agents.

GROUP THREE ELEMENTS
1.      They include B, Al, Ga, In and thallium
2.      They have three electrons in their outermost shell
3.      They form weakly electrovalent compounds with Non-metal
4.      Boron is a non- metal, forming covalent bond while Aluminium is a metal.

GROUP FOUR ELEMENTS
   Group 4 elements are quite mixed. Metallic properties increases down the group, while carbon is a non –metal, Silicon and Germanium are metalloids, Tin and Lead are metals.
            However, both Silicon and Lead form amphoteric oxides.
Group five elements
            This the Nitrogen family, Nitrogen is a gas at room temperature, Phosphorus is a solid, while Antimony and Bismuth are metals.
GROUP SIX ELEMENTS
1.      This group also include both non-metals and metals.
2.      Oxygen and Sulphur are non-metals while Selenium and Tellurium are metals.

GROUP SEVEN ELEMENTS
1.      They are popularly known as HALOGENS
2.      They include Fluorine, Chlorine, Bromine, Iodine and Astatine.
3.      They are highly electronegative
4.      They have seven electrons in their outer most shell.
5.      Their electronegativity decreases down the group. However, Fluorine is most Electronegative Element and the most reactive of all the elements.

GROUP EIGHT ELEMENTS:
1.      They are called the noble gases
2.      They are all gas at room temperature
3.      They include, Helium, Neon, Argon, Krypton, Xenon and Radon
4.      They have completely filled shell and hence, they are all unreactive.

TRANSITION ELEMENTS
Between group 2 and 3 is a block of elements which shows similar and strange behaviour the other metals. They are called the transition elements. They are all metals with metallic properties. Their strange behaviour include:
1.      Variable oxidation state
2.      Paramagnetic in nature
3.      Formation of coloured compound
4.      Catalytic ability.
5.      They include: Scandium, Titanium, Vanadium, Chromium, Manganese, Iron, Cobalt, Nickel, Zinc.

LANTHANIDE AND ACTINIDE
            Apart from the various groups of elements discussed so far, there are set of another element isolated below the periodic table. They are originally located between period six and seven. These elements are called the lanthanide and the actinide series respectively. (See the table above) they start from Lanthanum to Lawrencium.


Sunday 23 October 2016

LESSON 4: PARTICULATE NATURE OF MATTER

LESSON 4: PARTICULATE NATURE OF MATTER

Behavioural objectives: at the end of this lesson, you should be able to:
1.      Write the electronic configuration of the first 20 elements correctly, using S,P,D,F format 
2.      State the Dalton’s atomic theory and its modification
3.      Solve problems related to isotope and relative atomic mass
4.      Differentiate between, molecule, ions and atom.
5.      Define isotopes and give examples of element that exhibit isotopy. 

CONTENT

What is a matter? Matter is defined as anything that has mass and occupies space. However, matter consists of some particles which could be atom, molecules, or ions   
Atoms: This is the smallest indivisible particle of an element which can take part in a chemical reaction. 
Molecules; This is the smallest part of a substance which can have a separate existence and still possess the properties of the substance. E.g. the tiny pieces of slice bread, a drop of water, hair strand e.t.c
Ion: An ion is any atom or group of atom which possesses an electric charge. There are 2 types of ions which are
1.       Cat ion: this is a positive charged ion. e.g. Na+ , Ca2+ , Fe3+  and
2.       An ion: this is a negative charged ion.  e.g  Cl- ­ , No 3- , OH e.t.c
    There are natural phenomenon which can be used to support the statement that matter is made up of particles. These include
1.      Diffusion: it is the movement of molecules of a substance from a region of higher concentration to the region of lower concentration, until it is evenly distributed. E.g. movement of scent of perfumes, aroma of soup e.t.c
2.      Evaporation: it is the process whereby molecules of a liquid of  highest kinetic energy escape into the atmosphere through the surface of the liquid. e.g. evaporation of water.
3.      Osmosis: this is the movement of solvent molecule from the region of lower concentration to a region of higher concentration through a semi permeable membrane. E.g. movement of water molecule from the soil to the root of plant.
4.      Brownian motion
5.      Sublimation
                              
DALTONS ATOMIC THEORY AND ITS MODIFICATIONS

S/N
Dalton’s atomic theory
Modification
1
Matter is made up of small indivisible particle called atoms. 
Matter is made up of small particles, which might be proton, neutron or electron. 
2
Atom can neither be created nor destroyed.
Atom can be created and can be destroyed. During chemical reactions there is change in heat content of the atoms. Also radioactivity prove it.
3
The atoms of the same element are alike in every aspect and differ from atoms of all other elements. 
Isotopes prove it wrong as atoms of the same element can have different masses. Chlorine has two isotopes which are different in atomic mass but have the same atomic number.
4
Chemical compound were made by the union of small whole number of atoms.
Polymers [organic compounds] are made from large number of atoms joined together.
                          
ATOMIC STRUCTURE
Atoms are found to contain three types of particles which are protons, neutrons and electrons. It consists of centrally placed nucleus which is surrounded by a cloud of electrons.
            The nucleus contains proton and neutrons with mass of one each. Proton is positively charged, neutron is neutrally charged while electron is negatively charged.
The electron revolves round the nucleus in an orbital in order to neutralize the positive charge in the nucleus. The atom is electrically neutral because the number of electrons revolving round the nucleus is equals to the number of protons in the nucleus.

The table below indicates the properties of sub-atomic particles.
Particles
Proton
Neutron
Electron

Mass
1
1
1/1840
Charge
+1
No charge
-1





ELECTRONIC CONFIGURATION
            This refers to the way electrons are arranged outside and around the nucleus. The electrons are arranged in orbits known as shells.
            There are seven shells in all which are K,L,M,N,O,P&Q. These shells are sub-divided into orbitals called S,P,D,F orbitals.

ORBITAL TYPES IN A SHELL
Shell
K
L
M
N
Shell number
1
2
3
4
Orbital type
1s
2s, 2p
3s, 3p, 3d
4s,4p,4d,4f
Maximum electron
2
8
18
32
From the table above, we can see that K –shell have just one orbital which is S – orbital, and S – orbital can only take maximum electrons of two. Therefore K – shell can have 2 electrons, and for L shell, it has two orbital which are 2s and 2p respectively. P – orbital can take 6 electrons, if we add 6 to 2 it makes 8 electrons. Likewise for D- orbital and F – orbital which can take 10 and 14 electrons respectively.      
The sequence of filling up the orbitals with electrons is as follows:
1s, 2s 2p, 3s 3p, 4s 3d,  note: that 4s is filled before 3d because 4s energy level is lower than 3d energy level. Now let’s take a look at the electronic configuration of the first 20 elements.


Elements
Atomic number
Symbol
Configuration
Hydrogen
1
H
1s1
Helium
2
He
1s2
Lithium
3
Li
1s2,2s1
Beryllium
4
Be
1s2,2s2
Boron
5
B
1s2,2s2 2p1
Carbon
6
C
1s2,2s2 2p2
Nitrogen
7
N
1s2, 2s2 2p3
Oxygen
8
O
1s2, 2s2 2p4
Fluorine
9
F
1s2, 2s2 2p5
Neon
10
Ne
1s2, 2s2 2p6
Sodium
11
Na
1s2, 2s2 2p6, 3s1
Magnesium
12
Mg
1s2, 2s2 2p6, 3s2
Aluminium
13
Al
1s2, 2s2 2p6, 3s3
Silicon
14
Si
1s2, 2s2 2p6, 3s2 3p2
Phosphorus
15
P
1s2,2s2 2p6, 3s2 3p3
Sulphur
16
S
1s2,2s2 2p6, 3s2 3p4
Chlorine
17
Cl
1s2, 2s2 2p6, 3s2 3p5
Argon
18
Ar
1s2,2s2 2p6, 3s2 3p6
Potassium
19
K
1s2,2s2 2p6, 3s2 3p6, 4s1
Calcium
20
Ca
1s2,2s2 2p6, 3s2 3p6, 4s2